
Fuel costs and sustainability goals drive cement producers to use large amounts of secondary fuels. However, in comparison to fossil fuels these fuels typically have lower heating values and combustion characteristics that negatively impact the clinker forming process. The strategic use of oxygen provides a cost-effective means to combine high alternative fuel use targets with excellent operational results. The article describes the challenges posed by high alternative fuel rates and how oxygen is used to further increase the use of alternative fuels. A case study is presented that shows the beneficial impact of oxygen-enhanced combustion of alternative fuels.
The benefits of oxygen enrichment in cement kilns are well documented (1, 2). In the past, production increase was the main motivator for using oxygen if the plant's capacity to handle more flue gas was preventing further production increases. Injection of essentially pure oxygen removes nitrogen from the flue gas stream that is normally introduced with the combustion air. This frees up valuable flue gas capacity to be used for further production. In addition, enrichment with oxygen improves available heat for production and reduces flue gas losses.
Experience with oxygen injection shows demonstrated benefits to customers ranging from production increases of up to 25%, specific fuel savings of up to 5%, reduced specific dust losses and improved kiln stability as evidenced by clinker quality and kiln coating. Low investment costs and an easy implementation have made this technology an attractive solution for a short-term capacity deficit. Figure 1 shows kiln sizes and oxygen flow rates used successfully in various projects over the last 50 years.
Long-term experience with this application suggests that a yield of 3t to 4t of incremental clinker per ton of oxygen can be achieved at most plants, if the flue gas system capacity is preventing increase of production and the plant has no further bottlenecks towards processing more material. Oxygen injection provides a high degree of flexibility that can maximise profits when cement market conditions are favourable.
The use of oxygen for increased production tends only to be justified in periods of high industry kiln capacity utilisation where high margins associated with the incremental product cover the cost of oxygen and enable the desired return on the project investment. With the exception of retiring older, inefficient clinker production lines and increasing the production with oxygen injection at modern low-cost facilities, present day market conditions in most parts of the world are generally not supportive of oxygen use for the purpose of production increase.